New PDF release: A Critical Review of Equilibrium Data for Proton and Metal

By W.A. E. McBryde

ISBN-10: 0080223443

ISBN-13: 9780080223445

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Additional resources for A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes

Sample text

28 cond. 025 20 0 . 59 12 25 0 . 05 13 20 0 . 93 11 65D 25 0 . 46 20 0 . 13 13 35 0 . 81 - - 11 76A 17 500 25 0 . 2 25 0 . 18 20 0 . 1 (NaN0 3 ) 25 0 . 1 KN03 - 25 0 . 33 25 - 25 1 NaClO^ 25 0 . 85 17 - 11 500 Rej 59G Rej 62Aa 62C 11 11 61J 16 25 0 . 95 25 0 . 56 12, 20 0 . 08 1 4 b ,16 18a 621 13 18 14b 18b KiDt 62C 63A Ln O "· « ON Kj 03 Ln Ln o o> Ηί o CU o o jl)o (1)o (1)n (D (D hO hO hO hO hO ON ON ON ON ON ON CO ON ho U) « > > ON Ln ON hO M 62 f Ln Ln O si Ln Ln ON H< «vj I— ' -P>» CO Lo CO h-1 CO CO Ln hO H Ln Ln O N O WI U H si O si V O 0 > L n O > c o 4 > - ^ J C O - P ^ O^ UJ hO LO Ln Ln O h O C O C o C O - F» -^ 00 CO Ln 00 Ln H» H» o N> Ln ho 0> H CO VO Co Co Co Co 4>» m si sj oo o Ln co en o hO Ln o hO Ln CO LO Ln Ln hO ON J> 4>.

3 Pi - 1 7 . 5 11 59G 23i - 1 0 . 1 (Continued) Auxiliary Ligand A Metal Complex log K log ß log X Medium Temp. 64 Temp. 87 Dt NN Bis(carboxymethyl)dithiocarbamate Cu(II) MLA Toluene-3,4-Dithiol Zn(II) Pyrocatechol violet - log ß log X Medium Temp. Method 25 12 12 720 ? 1 KC1 25 12 720 ? 12 72Ga ? 1 KC1 ? 89 Dt - ? 1 KNO3 ? 2 Equilibrium Constants of Mixed Complexes 2,2f-Bipyridyl = L Auxiliary Ligand A Hydroxide Metal Complex Fe(III) M2(0H)2L4 Cu(II) MOHL log K log ß M 2 (0H) 2 L 2 Temp. Method Reference var.

58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq. 58 25 50% aq. 94 25 75% aq. 40 25 50% aq. 97 25 50% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq.

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A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes by W.A. E. McBryde


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