By Ilya Prigogine
The Advances in Chemical Physics sequence presents the chemical physics and actual chemistry fields with a discussion board for serious, authoritative reviews of advances in each region of the self-discipline. full of state of the art study pronounced in a cohesive demeanour now not came across in different places within the literature, every one quantity of the Advances in Chemical Physics sequence serves because the excellent complement to any complicated graduate classification dedicated to the research of chemical physics.
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Extra resources for Advances in Chemical Physics, Volume 19
1969. These studies commenced with the use of the ion sources of commercially available mass spectrometers as reaction chambers. This single-source technique generated data and questions which provided the impetus for development of more specialized apparatus such as the tandem mass spectrometer, and the ion cyclotron resonance and flowing afterglow techniques. Experiments based on these advances in technology have been used to develop a body of knowledge which can be divided into gaseous ion thermochemistry on the one hand and the dynamics of ion-molecule collision processes on the other, and we shall consider these separately.
One may think of the former as establishing necessary conditions which must be satisfied if a chemical change is to be observed in a collision 36 L. FRIEDMAN AND B. G . REUBEN process, and of the latter as providing information which can lead to data on the thermochemistry of gaseous ions. Returning to Figure 1, the period prior to 1950 may be thought of as the “one paper a year” era when the experimental facilities required for the study of ion collision processes were limited to a very few laboratories.
2. PolymerizationReactions . . 3. Addition Reactions . . . . 4. Clustering Reactions. . . . 5. Determination of Rate Constants in High Pressure Systems E. State Selection of Reactants . . 1. Introduction . . . . 2. Pulsed Source Techniques . . . 3. Flowing Afterglow . . . . 4. Photoionization . . F. Channels of Reaction . . . 1. Introduction . . . 2. Single Source and Tandem Mass Spectrometer Techniques 3. High Pressure Mass Spectrometry . 4. Ion Cyclotron Resonance Spectroscopy .
Advances in Chemical Physics, Volume 19 by Ilya Prigogine